Synthetic Polymers (Plastic, Resin)

Introduction

This page is divided up into 4 section. If this is your first time here, please start at the top and work your way down. For quick reference:

Caution on buttons containing Formaldehyde

Early Synthetic Polymers Identification

Modern Synthetic Polymers Identification

Synthetic Polymers Cleaning, Restoring, and Protection

AKA Man-made Polymer. Plastic is a man-made, synthetic or semi-synthetic material that is made of polymers—long chains of molecules—that can be molded into various shapes. It is derived mainly from petrochemicals like natural gas and oil, but can also be made from renewable materials like corn, cellulose or milk proteins.

Please view the CLEANING CAUTIONS section before proceeding. section before proceeding. Remember this information is a suggestion and you proceed at your own risk.

If the synthetic polymer buttons contains any paint or enamel, please see CLEANING BUTTONS WITH ENAMEL section on how to clean buttons with enameling before proceeding.

There are two types of polymer plastics; Thermoplastics and Thermosets.

Thermoplastics

Thermoplastics is one type of polymer plastic that becomes pliable when heated and solidifies upon cooling, allowing them to be repeatedly melted and reshaped. For buttons making Celluloid (both cellulose nitrate and cellulose acetate), ABS (acrylonitrile butadiene styrene), Nylon (polyamide resin), and Lucite (polymethyl methacrylate - PMMA) are the most popular thermoplastics used in buttons.

Thermosets

Thermosets harden when heated, forming strong, cross-linked bonds. Once it has cured, it cannot be remolded or reshaped by reheating, unlike thermoplastics. For early button making Bakelite (phenolic resin or phenol-formaldehyde resin), Catalin (phenol-formaldehyde resin), early Casein (formaldehyde milk protein), polyester resin and urea-formaldehyde resin are the most popular thermosetting plastics used in making buttons.

Early Synthetic Polymers Identification

The button collectors use the brand names for certain classification for early synthetic polymers.

Those brand name include:

Bakelite or Catalin (phenolic resin or phenol-formaldehyde resin)
Casein, Galalith, Lactoid, or Erinoid (formaldehyde milk protein)
Celluloid (cellulose nitrate)
Lavahorn (urea-formaldehyde)

Lucite (acrylic)

Generic - no brand name association:

Cellulose acetate
Urea (urea-formaldehyde)

The original Bakelite and Celluloid brands had initial problems. which were identified quickly and resulted in modified formulations or additional invention of different types of plastic.

Modern Synthetic Polymers Identification

Today, mass produced buttons are made mainly from ABS, Acrylic, Nylon, Phenolic Resin, Polyester / Polystyrene and Urea. The most common ones being polyester resin, ABS plastic, and nylon. There are other not so popular synthetic polymers such as acrylic shot, linoleum. melamine and polymer clay, which are used by many independent button makers.

Those modern synthetic polyers include:

ABS Resin (acrylonitrile butadiene styrene)
Acrylic (polymethyl methacrylate or PMMA)
Acrylic shot
Melamine melamine-formaldehyde resin
Nylon (polyamide resin)
Phenolic Resin (phenol-formaldehyde resin)
Polymer Clay (polyvinyl chloride or PVC)
Polyester (unsaturated polyester resin)
Polystyrene(unsaturated polyester resin)
Urea Resin (urea-formaldehyde)

Synthetic Polymers Cleaning, Restoring, and Protection

After identifying your synthetic polymers, select one of the following. If you still don't know select UNKNOWN

ABS Resin (Modern)
Acrylic (Modern)
Acrylic Shot (Vintage)
Bakelite (Early)
Casein, Galalith, Lactoid, or Erinoid (Early and Modern)
Catalin (Early and Modern)
Celluloid (Early)
Cellulose acetate (Early)
Lavahorn (MCM)
Lucite (Early)
Melamine (Modern)
Nylon (Modern)
Phenolic Resin (Modern)
Polymer Clay (Modern)
Polyester (Modern)
Polystyrene (Modern)
Urea
Urea Resin (Modern)

UNKNOWN